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Pentane storage and solvent blending under the Process Safety Management rule

Summary A requester asked whether large pentane storage and a solvent blending setup were exempt from OSHA’s Process Safety Management rule. OSHA did not decide either question on the facts supplied. It asked how the pentane was used and kept below its boiling point, and whether the solvent tanks and mixing containers were connected, emphasizing that a process can include storage, transfer, handling and interconnected use.
Document
Federal opinion letter
Agency
Occupational Safety and Health Administration (OSHA)
Document number
1992-12-03
Date issued
December 3, 1992
Status
Archived by the agency
OSHA marks this page as an archive document and says it may no longer represent OSHA policy.
Status last verified October 9, 2026

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NOTICE: This is an OSHA Archive Document, and may no longer represent OSHA Policy. It is presented here as historical content, for research and review purposes only.

December 3, 1992

Mr. David A. Day
[Recipient address omitted]
Dear Mr. Day:

This is in response to your July 14 letter to Mr. Rolland Stroup, a member of my staff requesting interpretations of the Occupational Safety and Health Administration (OSHA's) standard on Process Safety Management (PSM) of Highly Hazardous Chemicals. Please accept our apologies for the delay in responding.

In your letter you requested that OSHA clarify whether the PSM standard would apply to the storage of pentane in excess of 10,000 pounds (4535.9 kg) in a tank where the pentane is neither chilled nor refrigerated to keep it below its boiling point and the tank pressure does not exceed 0.5 psi (3447.3 newtons per square meter) gauge. We need additional information to determine applicability of the PSM standard. Please advise us how the pentane is used at the site, and how it is transferred. Also, since the boiling point of pentane is 97 degrees F, please advise how it is kept below that temperature on hot days. Please feel free to contact us for any further request for interpretation. Your careful consideration of the "process" definition in the PSM standard is recommended. Please note that a process may include not only storage and associated transfer activities but also, interconnected use, manufacturing, handling and on-site movement activities.

Also, in your letter you requested that OSHA clarify whether the following process is exempt from coverage by the PSM standard. A process involves n-propyl alcohol and n-propyl acetate used as solvents for printing inks. The solvents are stored in above ground tanks and are piped inside the building where the solvents are distributed into individual five gallon (18.9 liter) containers where the inks are mixed. These flammable liquids are stored in atmospheric tanks and transferred while being kept below their boiling point without benefit of chilling or refrigeration. Please advise us of the capacity of the storage tanks and if the five gallon (18.9 l) containers are directly connected to the incoming flammable liquids during the dispensing process. Are the containers then moved prior to the mixing?

Thank you for your interest in occupational safety and health. If we may be of further assistance, please contact us.

Sincerely,
Roger A. Clark,
Director
Directorate of Compliance Programs

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